4-Methyl-1-[4-(methylsulfanyl)benzylidene]thiosemicarbazide
نویسندگان
چکیده
The title compound, C(10)H(13)N(3)S(2), is roughly planar (r.m.s. deviation = 0.086 Å). In the crystal, N-H⋯S hydrogen bonds link the mol-ecules into (001) sheets.
منابع مشابه
4-Ethyl-1-[4-(methylsulfanyl)benzylidene]thiosemicarbazide
There are four independent mol-ecules in the asymmetric unit of the title compound, C(11)H(15)N(3)S(2), with different conformations: the dihedral angles between the benzene rings and thio-urea units are 16.85 (9), 0.56 (10), 8.05 (12) and 4.56 (8)°. Each mol-ecule contains an intra-molecular N-H⋯N hydrogen bond, generating an S(5) ring. The crystal structure is stabilized by inter-molecular N-...
متن کامل(5′′E)-1′′-Benzyl-1′-methyl-5′′-[4-(methylsulfanyl)benzylidene]-4′-[4-(methylsulfanyl)phenyl]dispiro[indoline-3,2′-pyrrolidine-3′,3′′-piperidine]-2,4′′-dione dichloromethane solvate
In the title compound, C(38)H(36)N(3)O(2)S(2)·CH(2)Cl(2), the 2-oxindole ring is almost planar (r.m.s. deviation = 0.032 Å), the pyrrolidine ring adopts a twist conformation and the piperidone ring exists as a chair. Three short C-H⋯O intra-molecular contacts occur. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯N inter-actions. The dichloro-methane solvent mol-ecule is disordered over ...
متن کامل(E)-3-Hydroxy-13-methyl-16-[4-(methylsulfanyl)benzylidene]-7,8,9,11,12,13,15,16-octahydro-6H-cyclopenta[a]phenanthren-17(14H)-one
In the title compound, C(26)H(28)O(2)S, the dihedral angles between the mean plane of the five membered ring and the 4-(methyl-sulfan-yl)benzyl-idine ring in the two crystallographically independent mol-ecules are 34.05 (10) and 40.53 (15)°. The packing is stabilized by inter-molecular O-H⋯O and C-H⋯O inter-actions.
متن کامل(E)-1-[4-(Dimethylamino)benzylidene]thiosemicarbazide
In the title mol-ecule, C(10)H(14)N(4)S, the thio-rea plane and benzene ring form a dihedral angle of 16.0 (3) Å. In the crystal structure, inter-molecular N-H⋯S hydrogen bonds link the mol-ecules into ribbons extended in the [100] direction; these incorporate inversion dimers.
متن کامل3-Methyl-4-{(E)-[4-(methylsulfanyl)benzylidene]amino}-1H-1,2,4-triazole-5(4H)-thione
In the title mol-ecule, C11H12N4S2, the dihedral angle between the triazole and benzene rings is 21.31 (5)°. A weak intra-molecular C-H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, pairs of N-H⋯S hydrogen bonds form inversion dimers. In addition, π-π inter-actions are observed between the benzene rings, with a centroid-centroid separation of 3.7599 (11) Å.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011